Development of a method for producing effective CdS/CdTe/Cu/Au solar elements on a flexible substrate designed for backup supplying systems prevention of emergency situations

Authors

DOI:

https://doi.org/10.15587/1729-4061.2021.247720

Keywords:

film photocell, flexible substrate, micromodule, solar cell, cadmium telluride, current-voltage characteristic

Abstract

The technology of forming film solar cells based on CdS / CdTe configuration of the "superstrat" type on a flexible substrate has been improved. To increase the efficiency of the developed solar cells on a flexible substrate, a chemical etching procedure in a nitrogen-phosphorus mixture was added to the traditional "chemical treatment". The conducted studies of the output parameters of the developed device structures showed that the highest values are observed in the case of chemical etching, both before the "chloride treatment" and after it. In the course of the study, it was found that a mandatory procedure in the formation of effective device structures is chemical etching in a nitrogen-phosphorus mixture both before the "chloride treatment" and after it. Carrying out the described procedures made it possible to obtain solar cells on a flexible substrate with an efficiency of 13.1 %. The increase in the efficiency of solar cells with two-stage chemical etching can be explained by the formation of excess tellurium on the surface, which leads to a decrease in resistance and, therefore, to a more efficient penetration of chlorine during the subsequent chloride treatment. Analysis of the transverse cleavage of the investigated device structures demonstrates significant grain growth and surface smoothness of the base layer, which ensures good adhesion with back contact. A study of the degradation resistance of the developed device structures during operation has been carried out. It was found that the obtained solar cells based on CdTe on a flexible substrate have a high degradation resistance and after 10 bending cycles there is no decrease in the output parameters. Thus, it has been established that chemical etching in a nitrogen-phosphorus mixture is a mandatory procedure for the formation of efficient solar cells on a flexible substrate.

Author Biographies

Iryna Borysenko, Central Research Institute of the Armed Forces of Ukraine

Assistant Scientific Secretary

Olexandr Burmenko, National University of Civil Defence of Ukraine

PhD

Department of Pyrotechnic and Special Training

Natalya Deyneko, National University of Civil Defence of Ukraine

Doctor of Technical Sciences, Associate Professor

Department of Special Chemistry and Chemical Engineering

Oleksandr Zobenko, Chornobyl Heroes of National University of Civil Protection of Ukraine

Department of Automatic Safety Systems and Electrical Installations

Yurii Yivzhenko, State Scientific Institution "Institute of Education Content Modernization"

PhD, Head of Sector

Sector of Scientific and Educational and Methodological Support for the Training of Professional Junior Bachelors in the System of Professional Pre-Higher Education of the Division of Scientific and Methodological Support of Vocational Education

Gennady Kamyshentsev, Administration of the State Border Guard Service of Ukraine

Doctor of Technical Sciences

Department of Regulatory and Organizational Work of the Personnel Management Department

Volodymyr Muraviov, State University of Infrastructure and Technologies

PhD, Associate Professor

Department of Artificial Intelligence and Telecommunication Technologies

Yuliia Mykhailovska, National University of Civil Defence of Ukraine

PhD

Department of Prevention Activities and Monitoring

Valerii Khrystych, National University of Civil Defence of Ukraine

PhD, Associate Professor

Department of Automatic Security Systems and Information Technologies

Svitlana Kryvonis, National Technical University «Kharkiv Polytechnic Institute»

Department of Physics

References

  1. Bonnet, D., Rabenhorst, H. (1972). New results on the development of a thin film p-CdTe–n-CdS heterojunction solar cell. In Proceedings of the 9th Photovoltaic Specialists Conference, 129–131.
  2. Yang, D., Yin, H. (2011). Energy Conversion Efficiency of a Novel Hybrid Solar System for Photovoltaic, Thermoelectric, and Heat Utilization. IEEE Transactions on Energy Conversion, 26 (2), 662–670. doi: https://doi.org/10.1109/tec.2011.2112363
  3. Leading Solar PV Manufacturers Based on Module Shipments in 2018 and 2019. Available at: https://www.statista.com/statistics/858456/global-companies-for-pv-cell-and-module-shipments/
  4. Rühle, S. (2016). Tabulated values of the Shockley–Queisser limit for single junction solar cells. Solar Energy, 130, 139–147. doi: https://doi.org/10.1016/j.solener.2016.02.015
  5. Bolbas, O., Deyneko, N., Yeremenko, S., Kyryllova, O., Myrgorod, O., Soshinsky, O. et. al. (2019). Degradation of CdTe SC during operation: modeling and experiment. Eastern-European Journal of Enterprise Technologies, 6 (12 (102)), 46–51. doi: https://doi.org/10.15587/1729-4061.2019.185628
  6. Deyneko, N., Kovalev, P., Semkiv, O., Khmyrov, I., Shevchenko, R. (2019). Development of a technique for restoring the efficiency of film ITO/CdS/CdTe/Cu/Au SCs after degradation. Eastern-European Journal of Enterprise Technologies, 1 (5 (97)), 6–12. doi: https://doi.org/10.15587/1729-4061.2019.156565
  7. First Solar sets world record for CdTe solar cell efficiency. Available at: https://investor.firstsolar.com/news/press-release-details/2014/First-Solar-Sets-World-Record-for-CdTe-Solar-Cell-Efficiency/default.aspx
  8. Wu, X., Dhere, R. G., Albin, D. S., Gessert, T. A., DeHart, C., Keane, J. C. et. al. (2001). High-Efficiency CTO/ZTO/CdS/CdTe Polycrystalline Thin-Film Solar Cells. To be presented at the NCPV Program Review Meeting Lakewood, Colorado. Available at: https://www.nrel.gov/docs/fy02osti/31025.pdf
  9. First Solar: Record 21.5 Percent Conversion Efficiency Research Cell Validates Technology Roadmap. Available at: https://www.sonnenseite.com/en/energy/first-solar-record-21-5-percent-conversion-efficiency-research-cell-validates-technology-roadmap/
  10. Green, M. A., Dunlop, E. D., Hohl‐Ebinger, J., Yoshita, M., Kopidakis, N., Hao, X. (2020). Solar cell efficiency tables (version 56). Progress in Photovoltaics: Research and Applications, 28 (7), 629–638. doi: https://doi.org/10.1002/pip.3303
  11. Van de Kaa, G., Rezaei, J., Kamp, L., de Winter, A. (2014). Photovoltaic technology selection: A fuzzy MCDM approach. Renewable and Sustainable Energy Reviews, 32, 662–670. doi: https://doi.org/10.1016/j.rser.2014.01.044
  12. Guanggen, Z., Jingquan, Z., Xulin, H., Bing, L., Lili, W., Lianghuan, F. (2013). The effect of irradiation on the mechanism of charge transport of CdTe solar cell. 2013 IEEE 39th Photovoltaic Specialists Conference (PVSC). doi: https://doi.org/10.1109/pvsc.2013.6745054
  13. Deyneko, N., Yeremenko, S., Kamyshentsev, G., Kryvulkin, I., Matiushenko, M., Myroshnyk, O. et. al. (2021). Development of a method for obtaining a CdS/CdTe/Cu/Au module on a flexible substrate designed for backup supplying systems prevention of emergency situations. Eastern-European Journal of Enterprise Technologies, 1 (5 (109)), 31–36. doi: https://doi.org/10.15587/1729-4061.2021.225694
  14. Mathew, X., Enriquez, J. P., Romeo, A., Tiwari, A. N. (2004). CdTe/CdS solar cells on flexible substrates. Solar Energy, 77 (6), 831–838. doi: https://doi.org/10.1016/j.solener.2004.06.020
  15. Tiwari, A. N., Romeo, A., Baetzner, D., Zogg, H. (2001). Flexible CdTe solar cells on polymer films. Progress in Photovoltaics: Research and Applications, 9 (3), 211–215. doi: https://doi.org/10.1002/pip.374
  16. Deyneko, N. (2020). Study of Methods for Producing Flexible Solar Cells for Energy Supply of Emergency Source Control. Materials Science Forum, 1006, 267–272. doi: https://doi.org/10.4028/www.scientific.net/msf.1006.267
  17. Burmenko, A., Deyneko, N., Hrebtsova, I., Kryvulkin, I., Prokopenko, O., Shevchenko, R., Tarasenko, O. (2020). Investigating an alternative electricity supply system for preventing emergencies under conditions of limited capacity. Eastern-European Journal of Enterprise Technologies, 3 (12 (105)), 56–61. doi: https://doi.org/10.15587/1729-4061.2020.206395
  18. Major, J. D., Treharne, R. E., Phillips, L. J., Durose, K. (2014). A low-cost non-toxic post-growth activation step for CdTe solar cells. Nature, 511 (7509), 334–337. doi: https://doi.org/10.1038/nature13435
  19. Green, M. A., Emery, K., Hishikawa, Y., Warta, W., Dunlop, E. D. (2015). Solar cell efficiency tables (version 46). Progress in Photovoltaics: Research and Applications, 23 (7), 805–812. doi: https://doi.org/10.1002/pip.2637
  20. Kestner, J. M., McElvain, S., Kelly, S., Ohno, T. R., Woods, L. M., Wolden, C. A. (2004). An experimental and modeling analysis of vapor transport deposition of cadmium telluride. Solar Energy Materials and Solar Cells, 83 (1), 55–65. doi: https://doi.org/10.1016/j.solmat.2004.02.013
  21. Deyneko, N., Semkiv, O., Khmyrov, I., Khryapynskyy, A. (2018). Investigation of the combination of ITO/CdS/CdTe/Cu/Au solar cells in microassembly for electrical supply of field cables. Eastern-European Journal of Enterprise Technologies, 1 (12 (91)), 18–23. doi: https://doi.org/10.15587/1729-4061.2018.124575
  22. Deyneko, N., Kryvulkin, I., Matiushenko, M., Tarasenko, O., Khmyrov, I., Khmyrova, A., Shevchenko, R. (2019). Investigation of photoelectric converters with a base cadmium telluride layer with a decrease in its thickness for tandem and two-sided sensitive instrument structures. EUREKA: Physics and Engineering, 5, 73–80. doi: https://doi.org/10.21303/2461-4262.2019.001002
  23. Lewis, J. (2006). Material challenge for flexible organic devices. Materials Today, 9 (4), 38–45. doi: https://doi.org/10.1016/s1369-7021(06)71446-8

Downloads

Published

2021-12-21

How to Cite

Borysenko, I., Burmenko, O., Deyneko, N., Zobenko, O., Yivzhenko, Y., Kamyshentsev, G., Muraviov, V., Mykhailovska, Y., Khrystych, V., & Kryvonis, S. (2021). Development of a method for producing effective CdS/CdTe/Cu/Au solar elements on a flexible substrate designed for backup supplying systems prevention of emergency situations. Eastern-European Journal of Enterprise Technologies, 6(5 (114), 6–11. https://doi.org/10.15587/1729-4061.2021.247720

Issue

Section

Applied physics