Devising a comprehensive technology for treating industrial iron sulfate-containing effluents of galvanic production

Authors

DOI:

https://doi.org/10.15587/1729-4061.2023.291383

Keywords:

electrodialysis, galvanic effluents, iron sulfate-containing solutions, three-chamber electrolyzer, ferrite method

Abstract

The object of the research is complex electrochemical and ferritic decontamination of iron sulfate-containing waters. Processing of liquid waste is carried out by electrochemical treatment using two- and three-chamber electrolyzers. This paper investigates the processes of electrodialysis purification of simulated solutions with an FeSO4 compound concentration of 5 g/dm3 and an H2SO4 compound concentration of 300–2100 mg-equiv/dm3. A plate made of stainless steel was used as the cathode, and a plate made of titanium covered with ruthenium oxide and lead was used as the anode. It is shown that the highest current yield of electrodialysis products of 84.5 % was obtained when using a three-chamber electrolyzer with MA-41 anion exchange membranes. It was found that when using the specified electrolyzer, the concentration gradient, the value of which is directly proportional to the difference in the concentrations of the initial solutions filled with the electrode chambers, has a significant effect on the process of separation of impurities. It is shown that for a two-chamber electrolyzer, the current output reaches 72 %, which is explained by the harmful effect of a significant concentration gradient and is manifested in the rapid mechanical blocking of the membrane and the slowing down of the ion migration process, as well as the increase in energy consumption. In a two-chamber electrolyzer, H2SO4 with a concentration of 18.3 % was obtained, which is suitable for repeated use in etching baths. It was found that as a result of electrodialysis separation and additional oxidation, it is advisable to use concentrated iron sulfate solutions for obtaining ferrite material of a crystalline structure with particle sizes of 2–20 μm. Within the framework of the circular economy, an ecologically safe technology for decontamination of industrial iron-containing sulfate solutions of galvanic production using a complex of electrodialysis and ferrite methods is proposed

Author Biographies

Serhii Dovholap, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute"

Postgraduate Student

Department of Ecology and Technology of Plant Polymers

Nikolai Gomelya, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute"

Doctor of Technical Sciences, Professor, Head of Department

Department of Ecology and Technology of Plant Polymers

Olena Ivanenko, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute"

Doctor of Technical Sciences, Associate Professor

Department of Ecology and Technology of Plant Polymers

Svetlana Frolenkova, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute"

PhD, Associate Professor

Department of Electrochemical Productions Technology

Tatiana Shabliy, National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute"

Doctor of Technical Sciences, Professor

Department of Ecology and Technology of Plant Polymers

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Devising a comprehensive technology for treating industrial iron sulfate-containing effluents of galvanic production

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Published

2023-12-22

How to Cite

Dovholap, S., Gomelya, N., Ivanenko, O., Frolenkova, S., & Shabliy, T. (2023). Devising a comprehensive technology for treating industrial iron sulfate-containing effluents of galvanic production. Eastern-European Journal of Enterprise Technologies, 6(10 (126), 17–26. https://doi.org/10.15587/1729-4061.2023.291383

Issue

Vol. 6 No. 10 (126) (2023): Ecology

Section

Ecology

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Copyright (c) 2023 Serhii Dovholap, Nikolai Gomelya, Olena Ivanenko, Svetlana Frolenkova, Tatiana Shabliy

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