Development of new C, S, N-containing plastic lubricants based on products from industrial waste integrated processing

Authors

DOI:

https://doi.org/10.15587/1729-4061.2024.296622

Keywords:

integrated technologies, industrial waste, plastic lubricants, bis-(diethyldithiocarbamate)copper(II), sorption, modified surface

Abstract

The object of this research is the integrated processing of industrial waste from various industries, which makes it possible to reduce the use of material and energy resources and improve the ecological state of the environment. Waste from the chemical, petrochemical, and machine-building industries was subject to integrated technological processing.

The common link that united the investigated complex technological cycles was the use of a regenerated mixed sorbent (activated carbon+kieselguhr), on the surface of which topochemical transformations of chemicals that were part of industrial waste took place. Using a regenerated mixed sorbent, exhausted industrial oil which was the mineral basis of the developed new C, S, N-containing plastic lubricants was purified. In particular, we have established the conditions for obtaining diethyl ammonium chloride from unusable pesticides of the formula R1R2R3R4C6HCOOH∙HN(C2H5)2, whose topochemical interaction on the surface of the mixed sorbent leads to the formation of a sorbed fragment [sorbent (activated carbon+kieselguhr)]∙[(C2H5)2NC(=S)SK]. Subsequent interaction of aqueous solutions containing copper(II) ions with such a fragment leads to the formation of bis–(diethyldithiocarbamate)copper(II) on the surface of mixed sorbent. The resulting substances of the general composition [sorbent (activated carbon + kieselguhr)]∙{[(С2H5)2NC(=S)S]2Cu} were studied as thickeners and active polyfunctional components of the obtained plastic lubricants. Research into the tribological properties of new C, S, N-containing plastic lubricants showed their high anti-wear and heat-resistant properties and the possibility of effective use in highly loaded friction nodes

Author Biographies

Anatoliy Ranskiy, Vinnytsia National Technical University

Doctor of Chemical Sciences, Professor

Department of Ecology, Chemistry and Environmental Protection Technologies

Olha Sandul, Vinnytsia National Technical University

Department of Ecology, Chemistry and Environmental Protection Technologies

Olga Gordienko, Vinnytsia National Technical University

PhD, Associate Professor

Department of Ecology, Chemistry and Environmental Protection Technologies

Natalia Didenko, National Pirogov Memorial Medical University

PhD, Associate Professor

Department of Pharmaceutical Chemistry

Taras Titov, Vinnytsia National Technical University

PhD

Department of Ecology, Chemistry and Environmental Protection Technologies

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Development of new C, S, N-containing plastic lubricants based on products from industrial waste integrated processing

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Published

2024-02-28

How to Cite

Ranskiy, A., Sandul, O., Gordienko, O., Didenko, N., & Titov, T. (2024). Development of new C, S, N-containing plastic lubricants based on products from industrial waste integrated processing. Eastern-European Journal of Enterprise Technologies, 1(6 (127), 13–21. https://doi.org/10.15587/1729-4061.2024.296622

Issue

Vol. 1 No. 6 (127) (2024): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2024 Anatoliy Ranskiy, Olha Sandul, Olga Gordienko, Natalia Didenko, Taras Titov

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