Establishing regularities of fire protection of wood by a composite coating with a biopolymer
DOI:
https://doi.org/10.15587/1729-4061.2025.332443Keywords:
fire retardant composition, biopolymers, wood surface treatment, surface tension, coating swellingAbstract
The object of this study is changes in the surface properties of wood during its treatment with a fire-retardant composite coating with the presence of biopolymers. The task, aimed at the production of environmentally friendly compositions obtained from natural and renewable sources for fire protection of wood and the application technology, is to ensure resistance to the action of high-temperature flames.
It has been proven that the fire-retardant composition with the presence of biopolymers is an accumulation of biological substances with nitrogen-phosphorus flame retardants, carbohydrates, and gas-forming substances, bordered by a polymer binder. Under the influence of thermal action, chemical reactions begin in the fire-retardant composition, ammonium polyphosphate decomposes and releases phosphoric acid. This, in turn, affects the destruction of the biopolymer and the dehydration of pentaerythritol with the formation of a large amount of hydrocarbons, and melamine causes the release of non-combustible gases, which induce the formation of foam coke.
A study of the surface energy characteristics of the fire-retardant composition with the presence of biopolymers was carried out and it was found that the polarity of the fire-retardant composition with the presence of biopolymers exceeds the value of untreated wood by 3.5 times, which provides effective treatment of the wood surface. According to the results of thermal exposure to the samples, it was found that under the action of the radiation panel, the fire-retardant composition swelled, when biopolymers such as wood flour and starch were added, the coke height increased by more than 15 mm, and the foam multiplicity increased by 1.2 times.
The practical significance is that the results were taken into account when designing a reactive coating for wood. Thus, there is reason to argue about the possibility of effective protection of wood with a fire retardant composition with the presence of biopolymers
References
- Pantaleoni, A., Marrocchi, A., Russo, P., Malucelli, G., Altamura, D., Nardelli, F. et al. (2025). Advanced flame-retardant biocomposites: Polylactic acid reinforced with green gallic acid‑iron‑phosphorus coated flax fibers. International Journal of Biological Macromolecules, 300, 140215. https://doi.org/10.1016/j.ijbiomac.2025.140215
- Li, M., Li, X., Xu, K., Qin, A., Yan, C., Xu, Y. et al. (2024). Construction and mechanism analysis of flame-retardant, energy-storage and transparent bio-based composites based on natural cellulose template. International Journal of Biological Macromolecules, 263, 130317. https://doi.org/10.1016/j.ijbiomac.2024.130317
- Melati, A., Settar, A., Alfano, A., Faucault, L., Chetehouna, K. (2023). Effect of Fire-Retardant Coating and SiC Powder Filler on Thermal Properties of Green-Poxy Bio-Based Composites. Advances in Thermal Science and Energy, 130–139. https://doi.org/10.1007/978-3-031-43934-6_14
- Li, S., Zhao, F., Wang, X., Liu, Z., Guo, J., Li, Y. et al. (2024). A green flame retardant coating based on one-step aqueous complexation of phytic acid and urea for fabrication of lightweight and high toughness flame retardant EPS insulation board. Polymer Degradation and Stability, 219, 110597. https://doi.org/10.1016/j.polymdegradstab.2023.110597
- Aghmih, K., Boukhriss, A., El Bouchti, M., Ait Chaoui, M., Majid, S., Gmouh, S. (2022). Introduction of Ionic Liquids as Highly Efficient Plasticizers and Flame Retardants of Cellulose Triacetate Films. Journal of Polymers and the Environment, 30 (7), 2905–2918. https://doi.org/10.1007/s10924-022-02407-3
- Madyaratri, E., Ridho, M., Aristri, M., Lubis, M., Iswanto, A., Nawawi, D. et al. (2022). Recent Advances in the Development of Fire-Resistant Biocomposites—A Review. Polymers, 14 (3), 362. https://doi.org/10.3390/polym14030362
- Rajendran, M., Nagarajan, C. kavitha. (2021). Experimental Investigation on bio-Composite Using Jute and Banana Fiber as a Potential Substitute of Solid Wood Based Materials. Journal of Natural Fibers, 19 (12), 4557–4566. https://doi.org/10.1080/15440478.2020.1867943
- Hanken, R. B. L., Arimatéia, R. R., Farias, G. M. G., Agrawal, P., Santana, L. N. L., Freitas, D. M. G., de Mélo, T. J. A. (2019). Effect of natural and expanded vermiculite clays on the properties of eco-friendly biopolyethylene-vermiculite clay biocomposites. Composites Part B: Engineering, 175, 107184. https://doi.org/10.1016/j.compositesb.2019.107184
- Giancaspro, J., Papakonstantinou, C., Balaguru, P. (2009). Mechanical behavior of fire-resistant biocomposite. Composites Part B: Engineering, 40 (3), 206–211. https://doi.org/10.1016/j.compositesb.2008.11.008
- Gómez, C., Torres, F. G., Nakamatsu, J., Arroyo, O. H. (2006). Thermal and Structural Analysis of Natural Fiber Reinforced Starch-Based Biocomposites. International Journal of Polymeric Materials and Polymeric Biomaterials, 55 (11), 893–907. https://doi.org/10.1080/00914030500522547
- Pettersen, R. C. (1984). The Chemical Composition of Wood. The Chemistry of Solid Wood, 57–126. https://doi.org/10.1021/ba-1984-0207.ch002
- Broido, A. (1969). A simple, sensitive graphical method of treating thermogravimetric analysis data. Journal of Polymer Science Part A-2: Polymer Physics, 7 (10), 1761–1773. https://doi.org/10.1002/pol.1969.160071012
- Traciak, J., Fal, J., Żyła, G. (2021). 3D printed measuring device for the determination the surface tension of nanofluids. Applied Surface Science, 561, 149878. https://doi.org/10.1016/j.apsusc.2021.149878
- Rekiel, E., Zdziennicka, A., Jańczuk, B. (2021). Mutual influence of ethanol and surfactin on their wetting and adhesion properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 627, 127161. https://doi.org/10.1016/j.colsurfa.2021.127161
- Tsapko, Y., Tkachenko, T., Tsapko, А., Likhnyovskyi, R., Sukhanevych, M., Bereznutska, Y. et al. (2024). Defining patterns in the fire protection of wood with reactive coating. Eastern-European Journal of Enterprise Technologies, 6 (10 (132)), 55–63. https://doi.org/10.15587/1729-4061.2024.317334
- Tsapko, J., Tsapko, А. (2017). Simulation of the phase transformation front advancement during the swelling of fire retardant coatings. Eastern-European Journal of Enterprise Technologies, 2 (11 (86)), 50–55. https://doi.org/10.15587/1729-4061.2017.73542
- Tsapko, Y., Tsapko, А., Bondarenko, O. (2019). Effect of a flameretardant coating on the burning parameters of wood samples. Eastern-European Journal of Enterprise Technologies, 2 (10 (98)), 49–54. https://doi.org/10.15587/1729-4061.2019.163591
- Tsapko, Y., Tsapko, А., Bondarenko, O. (2020). Modeling the process of moisture diffusion by a flame-retardant coating for wood. Eastern-European Journal of Enterprise Technologies, 1 (10 (103)), 14–19. https://doi.org/10.15587/1729-4061.2020.192687
- Tsapko, Y. V., Tsapko, A., Bondarenko, O. P., Sukhanevych, M. V., Kobryn, M. V. (2019). Research of the process of spread of fire on beams of wood of fire-protected intumescent coatings. IOP Conference Series: Materials Science and Engineering, 708 (1), 012112. https://doi.org/10.1088/1757-899x/708/1/012112
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Yuriy Tsapko, Аleksii Tsapko, Ruslan Likhnyovskyi, Kseniia Bielikova, Oksana Berdnyk, Andrii Gavryliuk, Anna Borysova, Oleksandr Dotsenko, Maksym Haiduk, Viacheslav Nesterenko

This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.
A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.





