Analysis of the total rheological model of the polymer melt flow
DOI:
https://doi.org/10.15587/1729-4061.2015.38951Keywords:
non-Newtonian fluid, rheology, flow model, relaxation, polymer melt, viscosity, flow rate, "sharkskin"Abstract
Plastics processing is regulated by the shear strain rate, so developing the flow models in a wide range of shear rates is an urgent task.
A comparative analysis of the total rheological curves of the polymer melt flows using two flow models was performed. The Levanichev "slug" flow model is based on a physical model and assumes that the non-Newtonian flow area occurs when the melt flow rate approximates to the relaxation rate. The Carreau model is semi-empirical, viscosity limit values and relaxation time are taken into account, non-Newtonian flow area is described by the flow index.
As a result of the analysis, the viscosity prediction errors were identified, and advantages of the "slug" flow model were shown. The method for calculating the flow of non-Newtonian fluid, where viscosity is understood as a change in the interaction area, resistance to the melt compression and overcoming melt adhesion to the channel walls was given, a new viscosity dimension was proposed.
A number of effects that arise during the plastics processing and engineering methods based on the physical model, describing the total rheological curve ("sharkskin", "diedroop", "discopurgeprocedure") was qualitatively considered.
References
- Rauwendaal, C.; Volodin, V. (Ed.) (2008). Identification and elimination of problems in extrusion. St. Petersburg.: Profession, 328. [in Russian]
- Rauvendal, K.; Malkin A. J. (Ed.) (2008). Рolymer extrusion. St. Petersburg.: Profession, 768.
- Tadmor, Z., Gogos, C. (1984). Theoretical Foundations of polymer processing. tr. from english Moscow, USSR, Chemistry, 632. [in Russian]
- Hammarström, D. (2004). A Model for Simulation of Fiber Suspension Flows. KTH Mechanics, Royal Institute of Technology SE-10044 Stockholm, Sweden, 125.
- Vinogradov, G. V., Malkin, A. J. (1977). Rheology of polymers. Moscow, USSR, Chemistry, 434.
- Dyadichev, V. V., Levanichev, V. V., Tereshtchenko, T. M. (2003). Method description rheology of the polymer melt in a wide range of shear rates. Resource-saving technologies of production and fabrication of materials in mechanical engineering. Lugansk: publ EUNU. Dal, 68–72.
- Wei, C., Yaqiang, S., Chunqian, L., Qian, L., Changyu, S. (2011). Effect of micro-viscosity and wall slip on polymer melt rheology inside micro-channel. Materials conference ANTEC 2011. Available at: http://www.plasticsengineering.org/polymeric/node/4897
- Hatzikiriakos, S. G., Dealy, J. M. (1991). Wall slip of molten high density polyethylene. I. Sliding plate rheometer studies. Department of Chemical Engineering, McGill University, Montreal, Canada. Available at: http://www.chem.mtu.edu/~fmorriso/cm4655/Hazikiriakos_Dealy.pdf
- Levanichev, V. (2013). Model of the polymer melt flow. Eastern-European Journal of Enterprise Technologies, 4/7(64), 39–41. Available at: http://journals.uran.ua/eejet/article/view/16685/14175
- Levanichev, V. (2014). Study of multi-layer flow in coextrusion processes. TEKA Commission of motorization and power industry in agriculture, 14 (1), 144–153. Available at: http://www.pan-ol.lublin.pl/wydawnictwa/TMot14_1/Teka_14_1.pdf
- Tager, A. A. (2007). Physical chemistry of polymers. 4th edition. Moscow, Scientific World, 576.
- Brian Black, W. (2000). Wall slip and boundary effects in polymer shear flows. A dissertation at the University of Wisconsin – Madison. Available at: http://grahamgroup.che.wisc.edu/pub/black_dissert.pdf
- Disco purge procedure for extrusion coaters (2010). The official website of the company Du Pont. Available at: http://www2.dupont.com/Nucrel/en_US/assets/downloads/disco_purge.pdf
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2015 Виталий Валерьевич Леваничев
This work is licensed under a Creative Commons Attribution 4.0 International License.
The consolidation and conditions for the transfer of copyright (identification of authorship) is carried out in the License Agreement. In particular, the authors reserve the right to the authorship of their manuscript and transfer the first publication of this work to the journal under the terms of the Creative Commons CC BY license. At the same time, they have the right to conclude on their own additional agreements concerning the non-exclusive distribution of the work in the form in which it was published by this journal, but provided that the link to the first publication of the article in this journal is preserved.
A license agreement is a document in which the author warrants that he/she owns all copyright for the work (manuscript, article, etc.).
The authors, signing the License Agreement with TECHNOLOGY CENTER PC, have all rights to the further use of their work, provided that they link to our edition in which the work was published.
According to the terms of the License Agreement, the Publisher TECHNOLOGY CENTER PC does not take away your copyrights and receives permission from the authors to use and dissemination of the publication through the world's scientific resources (own electronic resources, scientometric databases, repositories, libraries, etc.).
In the absence of a signed License Agreement or in the absence of this agreement of identifiers allowing to identify the identity of the author, the editors have no right to work with the manuscript.
It is important to remember that there is another type of agreement between authors and publishers – when copyright is transferred from the authors to the publisher. In this case, the authors lose ownership of their work and may not use it in any way.