A study of environmentally friendly recycling of technogenic chromium and nickel containing waste by the method of solid phase extraction

Authors

DOI:

https://doi.org/10.15587/1729-4061.2018.121615

Keywords:

waste processing, corrosion-resistant steel, carbon thermal reduction, phase analysis, microstructure, resource efficiency

Abstract

The study has revealed the regularities of the effect produced by increasing the content of scale of steel 12Cr18Ni10Ti in the charge from 5 to 75 mass % on the contents of the products of carbon thermal reduction of oxide waste of corrosion-resistant steels. The concentration of Ni is increased from 0.8 to 7.0 mass % when the Cr content ranges from 15.9 to 17.1 mass %. The concentration of Cr in the extraction products within the range of 16.1–17.1 mass% is provided with the content of scale of 95Cr18 steel in the charge in the range from 5 to 55 mass %. It has been found that metallization products mainly consist of a solid solution of alloying elements in α-Fe. Fe3O4, Fe3C, and Fe2C were also identified. The microstructure of the extraction products is spongy and disordered. The particles are sintered, with varying Cr and Ni contents in the ranges of 7.47 to 18.03 mass % and 2.97–10.40 mass %, respectively. The study has helped achieve environmentally safe conditions for solid-phase extraction of chrome and nickel containing industrial wastes from the production of corrosion-resistant steels with the return of the alloyed product to the welding industry

Author Biographies

Stanislav Hryhoriev, Zaporizhzhya National University Zhukovskoho str., 66, Zaporizhzhya, Ukraine, 69600

Doctor of Technical Sciences, Professor

Department of business administration and international management

Artem Petryshchev, Zaporizhzhya National Technical University Zhukovskoho str., 64, Zaporizhzhya, Ukraine, 69063

PhD, Associate Professor

Department of Labour and Environment Protection

Ganna Shyshkanova, Zaporizhzhya National Technical University Zhukovskoho str., 64, Zaporizhzhya, Ukraine, 69063

PhD, Associate Professor

Department of Applied Mathematics 

Tetyana Zaytseva, Oles Honchar Dnipro National University Haharina ave., 72, Dnipro, Ukraine, 49010

PhD, Associate Professor

Department of Computer Technologies 

Oleksandr Frydman, Oles Honchar Dnipro National University Haharina ave., 72, Dnipro, Ukraine, 49010

PhD, Associate Professor

Department of Statistics and Probability Theory 

Kristina Krupey, Zaporizhzhya National University Zhukovskoho str., 66, Zaporizhzhya, Ukraine, 69600

PhD, Assistant

Department of General and Applied Ecology and Zoology

Andrey Andreev, Zaporizhzhya National University Zhukovskoho str., 66, Zaporizhzhya, Ukraine, 69600

PhD, Associate Professor

Department of physics and methods of teaching

Alexander Katschan, Zaporizhzhya National Technical University Zhukovskoho str., 64, Zaporizhzhya, Ukraine, 69063

Senior Lecturer

Department of software development

Yuliya Petrusha, Zaporizhzhya National University Zhukovskoho str., 66, Zaporizhzhya, Ukraine, 69600

PhD, Associate Professor

Department of Chemistry

Dmytro Stepanov, Zaporizhzhya National Technical University Zhukovskoho str., 64, Zaporizhzhya, Ukraine, 69063

Senior Lecturer

Department of technology of mechanical engineering

References

  1. Puchol, R. Q., Sosa, E. R., González, L. O., Castañeda, Y. P., Sierra, L. Y. (2016). New conception of the reutilization of solid waste from Cuban nickeliferous hydrometallurgical industry. Centro Azucar, 43 (4), 1–15.
  2. Pincovschi, I., Neacsu, N., Modrogan, C. (2017). The Adsorbtion of Lead, Copper, Chrome and Nickel Ions from Waste Waters in Agricultural Argilaceous Soils. Revista de Chimie, 68 (4), 635–638.
  3. Madebwe, V., Madebwe, C., Munodawafa, A., Mugabe, F. (2017). Analysis of the Spatial and Temporal Variability of Toxic Heavy Metal Concentrations in Ground Water Resources in Upper Sanyati Catchment, Midlands Province, Zimbabwe. IIARD International Journal of Geography and Environmental Management, 3 (1), 23–37.
  4. Rubezhniak, I. H. (2016). Porivnialna otsinka normatyviv zabrudnennia gruntiv vazhkymy metalamy v Ukraini ta krainakh EU. Naukovyi visnyk Natsionalnoho universytetu bioresursiv i pryrodokorystuvannia Ukrainy. Seriya: Biolohiya, biotekhnolohiya, ekolohiya, 234, 228–238.
  5. Atanassov, I. (2008). New bulgarian soil pollution standards. Bulgarian Journal of Agricultural Science, 14, 68–75.
  6. Eastmond, D. A., MacGregor, J. T., Slesinski, R. S. (2008). Trivalent Chromium: Assessing the Genotoxic Risk of an Essential Trace Element and Widely Used Human and Animal Nutritional Supplement. Critical Reviews in Toxicology, 38 (3), 173–190. doi: 10.1080/10408440701845401
  7. Itankar, N., Patil, Y. (2014). Management of Hexavalent Chromium from Industrial Waste Using Low-cost Waste Biomass. Procedia – Social and Behavioral Sciences, 133, 219–224. doi: 10.1016/j.sbspro.2014.04.187
  8. Chervona, Y., Arita, A., Costa, M. (2012). Carcinogenic metals and the epigenome: understanding the effect of nickel, arsenic, and chromium. Metallomics, 4 (7), 619. doi: 10.1039/c2mt20033c
  9. Ryabchikov, I. V., Belov, B. F., Mizin, V. G. (2014). Reactions of metal oxides with carbon. Steel in Translation, 44 (5), 368–373. doi: 10.3103/s0967091214050118
  10. Mechachti, S., Benchiheub, O., Serrai, S., Shalabi, M. (2013). Preparation of iron Powders by Reduction of Rolling Mill Scale. International Journal of Scientific & Engineering Research, 4 (5), 1457–1472.
  11. Roshchin, V. E., Roshchin, A. V., Ahmetov, K. T., Povolotskiy, V. D., Goyhenberg, Yu. N. (2015). Formirovanie metallicheskoy i karbidnyh faz pri poluchenii uglerodistogo ferrohroma: teoriya i eksperiment. Problemy chernoy metallurgii i materialovedeniya, 1, 5–18.
  12. Kolesnikov, A. S., Nazarbekova, S. P., Baibolov, K. S., Dzholdasova, S. A. (2017). Thermodynamic simulation of chemical and phase transformations in the Fe2O3–NiO–CoO–C. Izvestiya Vuzov Tsvetnaya Metallurgiya (Proceedings of Higher Schools Nonferrous Metallurgy, 3, 37–44. doi: 10.17073/0021-3438-2017-3-37-44
  13. Kovalov, A. M., Petryshchev, A. S., Hryhorev, S. M. (2010). Analiz termodynamichnoi rivnovahy v systemi Ni–Co–O–C–H stosovno tekhnolohiyi metalizatsiyi metalooksydnykh tekhnohennykh vidkhodiv pretsyziinykh splaviv typu NK. Naukovi pratsi Donetskoho natsionalnoho tekhnichnoho universytetu. Seriya: Metalurhiya, 12, 7–15.
  14. Pan, J., Zheng, G., Zhu, D., Zhou, X. (2013). Utilization of nickel slag using selective reduction followed by magnetic separation. Transactions of Nonferrous Metals Society of China, 23 (11), 3421–3427. doi: 10.1016/s1003-6326(13)62883-6
  15. Simonov, V. K., Grishin, A. M. (2015). Termodinamicheskiy analiz i osobennosti kinetiki vosstanovleniya Cr2O3 uglerodom samostoyatel'no i v potoke SO, N2. Elektrometallurgiya, 9, 9–18.
  16. Akimov, E. V., Senin, A. V., Roshchin, V. E. (2013). Termodinamicheskiy analiz polucheniya nizkouglerodistogo ferrohroma s primeneniem modeli assotsiirovannyh rastvorov. Vestnik Yuzhno-Ural'skogo gosudarstvennogo universiteta. Seriya: Metallurgiya, 13 (1), 182–185.
  17. Simonov, V. K., Grishin, A. M. (2012). Termodinamicheskiy analiz i osobennosti mekhanizma tverdofaznogo vosstanovleniya Cr2O3 uglerodom. Ch. 1. Elektrometallurgiya, 9, 21–26.
  18. Simonov, V. K., Grishin, A. M. (2012). Termodinamicheskiy analiz i osobennosti mekhanizma tverdofaznogo vosstanovleniya Cr2O3 uglerodom. Ch. 2. Elektrometallurgiya, 10, 13–18.
  19. Zhao, L., Wang, L., Chen, D., Zhao, H., Liu, Y., Qi, T. (2015). Behaviors of vanadium and chromium in coal-based direct reduction of high-chromium vanadium-bearing titanomagnetite concentrates followed by magnetic separation. Transactions of Nonferrous Metals Society of China, 25 (4), 1325–1333. doi: 10.1016/s1003-6326(15)63731-1

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Published

2018-01-24

How to Cite

Hryhoriev, S., Petryshchev, A., Shyshkanova, G., Zaytseva, T., Frydman, O., Krupey, K., Andreev, A., Katschan, A., Petrusha, Y., & Stepanov, D. (2018). A study of environmentally friendly recycling of technogenic chromium and nickel containing waste by the method of solid phase extraction. Eastern-European Journal of Enterprise Technologies, 1(10 (91), 44–49. https://doi.org/10.15587/1729-4061.2018.121615