Research on oxidative stability of protein-fat mixture based on sesame and flax seeds for use in halva technology

Authors

  • Anna Belinska Ukrainian Scientific Research Institute of Oils and Fats of the National Academy of Agricultural Sciences of Ukraine Dziuby ave., 2A, Kharkiv, Ukraine, 61019, Ukraine https://orcid.org/0000-0001-5795-2799
  • Sergiy Bochkarev National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002, Ukraine https://orcid.org/0000-0003-4399-7907
  • Oleksandra Varankina National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002, Ukraine https://orcid.org/0000-0002-6117-7091
  • Vasyl Rudniev Hon. Prof. M. S. Bokarius Kharkiv Research Institute of Forensic Examinations Zolochivska str., 8a, Kharkiv, Ukraine, 61177, Ukraine https://orcid.org/0000-0002-2550-3515
  • Oksana Zviahintseva National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002, Ukraine https://orcid.org/0000-0003-1921-4204
  • Kateryna Rudnieva Hon. Prof. M. S. Bokarius Kharkiv Research Institute of Forensic Examinations Zolochivska str., 8a, Kharkiv, Ukraine, 61177, Ukraine https://orcid.org/0000-0002-7676-749X
  • Iryna Bielykh National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002, Ukraine
  • Vadym Khosha Hon. Prof. M. S. Bokarius Kharkiv Research Institute of Forensic Examinations Zolochivska str., 8a, Kharkiv, Ukraine, 61177, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2019.178908

Keywords:

sesame, flax, sesamol, sesamolin, -linolenic acid, protein-fat mixture, oxidative damage, antioxidants, sunflower halva

Abstract

The analysis of the main methods of modeling the formulations of protein-fat mixtures for special purposes has been conducted. Considerable attention is paid to the choice of methods for stabilizing their lipid component from oxidative damage. The urgency of increasing the oxidative stability of the protein-fat mixtures due to natural antioxidants is emphasized. The feasibility of comprehensive studies of their effect on the stability to oxidation of the most labile biologically active substances of protein-fat mixtures is substantiated.

The content of furan antioxidants in the sesame seeds of Ilona, Kadet, Boyarin varieties has been determined. The correlation between the content of free and bound sesamol (sesamolin) has been determined. The content of a-linolenic acid and tocopherols in seeds of Southern Night, Kivik, Sympatik flax varieties has been also investigated. The choice of sesame and flax varieties for the creation of protein-fat mixture for special-purpose, which is a source of w-3 group polyunsaturated fatty acids and antioxidants (sesamol and sesamolin), is justified.

The effect of sesamolin content and moisture in the seeds of Ilona variety sesame on the oxidation resistance of its lipid component has been studied. A mathematical dependence describing such effect has been obtained. A regularity of increasing oxidation stability of sesame lipids with increasing its moisture content from 4.0 to 9.5 % has been revealed. This can be explained by sesamolin hydrolysis intensification with the release of sesamol and samin antioxidants.

The stabilization effect of a-linolenic acid of flaxseed (Southern Night variety) by free sesame sesamol in the protein-fat mixture for special-purpose has been studied. It has been proved that a rational ratio of w-3 fatty acids and sesamol has a significant effect on the inhibition of lipid oxidation of the protein-fat mixture for special purposes.

The content of the protein-fat mixture for special-purpose in sunflower halva at the level of 20 % has been substantiated using a sensory evaluation method. The oxidative stability, organoleptic and physicochemical quality control parameters of the product have been investigated. It has been determined that the oxidation stability (and, accordingly, the predicted shelf life) of model samples of sunflower halva depend on the content of protein-fat mixture in them

Author Biographies

Anna Belinska, Ukrainian Scientific Research Institute of Oils and Fats of the National Academy of Agricultural Sciences of Ukraine Dziuby ave., 2A, Kharkiv, Ukraine, 61019

PhD, Researcher

Department of Studies of Technology for Processing Oils and Fats

Sergiy Bochkarev, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

Senior Lecturer

Department of Physical Education

Oleksandra Varankina, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Associate Professor

Department of Biotechnology, Biophysics and Analytical Chemistry

Vasyl Rudniev, Hon. Prof. M. S. Bokarius Kharkiv Research Institute of Forensic Examinations Zolochivska str., 8a, Kharkiv, Ukraine, 61177

PhD, Leading Researcher

Laboratory of Forensic Examination

Oksana Zviahintseva, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Associate Professor

Department of Biotechnology, Biophysics and Analytical Chemistry

Kateryna Rudnieva, Hon. Prof. M. S. Bokarius Kharkiv Research Institute of Forensic Examinations Zolochivska str., 8a, Kharkiv, Ukraine, 61177

Forensic Expert

Laboratory of Forensic Examination

Iryna Bielykh, National Technical University «Kharkiv Polytechnic Institute» Kyrpychova str., 2, Kharkiv, Ukraine, 61002

PhD, Associate Professor

Department of Biotechnology, Biophysics and Analytical Chemistry

Vadym Khosha, Hon. Prof. M. S. Bokarius Kharkiv Research Institute of Forensic Examinations Zolochivska str., 8a, Kharkiv, Ukraine, 61177

PhD, Head of Department

Department of Postgraduate and Doctoral Studies

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Published

2019-09-24

How to Cite

Belinska, A., Bochkarev, S., Varankina, O., Rudniev, V., Zviahintseva, O., Rudnieva, K., Bielykh, I., & Khosha, V. (2019). Research on oxidative stability of protein-fat mixture based on sesame and flax seeds for use in halva technology. Eastern-European Journal of Enterprise Technologies, 5(11 (101), 6–14. https://doi.org/10.15587/1729-4061.2019.178908

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Section

Technology and Equipment of Food Production