Obtaining glucose-based 5-hydroxymethylfurfural on large-pore zeolites

Authors

DOI:

https://doi.org/10.15587/1729-4061.2021.226575

Keywords:

large-pore zeolites, polycationic forms, glucose dehydration, 5-hydroxymethylfurfural, yield, glucose conversion

Abstract

Obtaining such substances-platforms as, in particular, 5-hydroxymethylfurfural is one of the areas most actively investigated at present. They can act as raw materials for the further production of a new generation of biopolymers, fuels, pharmaceuticals, dietary supplements, and other chemicals. This paper reports the catalysts, synthesized by using methods of ion exchange and impregnation, based on the large-pore zeolites X, Y, and M, which contain the cations of rubidium, lanthanum, calcium, and ammonium. It was found that the zeolites' specific surface was 400‒500 m2/g; the selected synthesis conditions did not cause noticeable destruction of the microporous structure. In the presence of the synthesized catalysts, glucose dehydration in the aqueous medium and in dimethyl sulfoxide was carried out at 150–160 °C. The higher efficiency of polycationic forms of zeolites in a non-aqueous medium has been established. In the latter case, a 40 % yield of 5-hydroxymethylfurfural was achieved at an almost complete glucose conversion. Deactivated catalyst samples were investigated using the methods of infrared spectroscopy and differential thermal analysis/thermogravimetry. It was found that the catalyst accumulates fewer oligomerization process by-products when the reaction is implemented in dimethyl sulfoxide. The loss of mass by the samples deactivated in an aqueous medium is 30‒33 %, while in dimethyl sulfoxide – up to 24 %. The obtained results are important for practical application as the only volatile conversion product is 5-hydroxymethylfurfural with a yield of up to 40 %. That is acceptable for the possible implementation of a one-stage process of obtaining 5-hydroxymethylfurfural in the future

Author Biographies

Lyubov Patrylak, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”

Doctor of Chemical Sciences, Professor

Department of Technology of Inorganic Substances, Water Treatment and General Chemical Technology

Serhii Konovalov, V. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry NAS of Ukraine

PhD

Department of Catalytic Synthesis

Olexandra Pertko, V. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry NAS of Ukraine

PhD

Department of Catalytic Synthesis

Anzhela Yakovenko, V. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry NAS of Ukraine

PhD

Department of Catalytic Synthesis

Volodymyr Povazhnyi, V. P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry NAS of Ukraine

PhD

Department of Catalytic Synthesis

Oleksandr Melnychuk, LLC "Fluid Management Systems"

PhD

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Published

2021-04-12

How to Cite

Patrylak, L., Konovalov, S., Pertko, O., Yakovenko, A., Povazhnyi, V., & Melnychuk, O. (2021). Obtaining glucose-based 5-hydroxymethylfurfural on large-pore zeolites . Eastern-European Journal of Enterprise Technologies, 2(6 (110), 38–44. https://doi.org/10.15587/1729-4061.2021.226575

Issue

Vol. 2 No. 6 (110) (2021): Technology organic and inorganic substances

Section

Technology organic and inorganic substances

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Copyright (c) 2021 Любовь Казимировна Патриляк, Сергей Викторович Коновалов, Александра Петровна Пертко, Анжела Викторовна Яковенко, Владимир Ананьевич Поважный, Александр Владимирович Мельничук

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