Development of potentiometric sensors for determining the concentration of ethan-1,2-dicarboxylic and 2-hydroxybenzoic acids

Authors

  • Kateryna Matorina Oles Honchar Dnipropetrovsk National University Gagarina 72, Dnipropetrovsk, Ukraine, 49010, Ukraine https://orcid.org/0000-0002-4168-0159
  • Olena Podpletnia State establishment «Dnipropetrovsk Medical Academy» Dzerzhinsky str., 9, Dnipropetrovsk, Ukraine, 49044, Ukraine

DOI:

https://doi.org/10.15587/1729-4061.2016.75385

Keywords:

potentiometry, sensor, succinic acid, salicylic acid, ion associate, food, kvass, red wine, walnut leaves, pharmaceuticals

Abstract

The study suggests developed potentiometric sensors for determining the concentration of succinic and salicylic acids through using ion associates of succinic acid with safranin T and salicylic acid with safranin T as an electrode­active material of a plasticized film membrane. It is an important task of analytic practice to determine the contents of succinic and salicylic acids in samples with a complex matrix (the environment, foodstuffs, and pharmaceuticals). The research has revealed analytical electrode characteristics of the designed sensors: the dynamic range (4–7 and 3–8 pC); the electrode function slope of 31 and 49 mV/pC; the minimum detectable concentration of Сmin=9·10­9 mol/L and 8·10­8 mol/L; the optimum pH range of 5.5–8.0 in the sensors operation; the conditioning time of 24 hours; the response time of 1–2 min; the lifetime of 11 months, respectively, for succinic acid and salicylic acid. We have found the selectivity coefficients (Ksel) for the devised sensors by the method of individual solutions with respect to carboxylic acids (citrate (1.0·10­3), tartaric (1.0·10­1), oxalic (3.0·10­3), and acetic (2.0·10­3)). The method of additives was used to find the succinic acid content in samples of kvass (sr=4.0 %), red wine (sr=5.0 %), walnut leaves (sr=5.8 %), whereas salicylic acid was studied in salicylic ointment (sr=4.6 %) and the solution of salicylic acid and resorcinol (sr=4.0 %). The correctness of the results was tested by the alternative alkalimetry method. The reproducibility of the suggested ionometric and alternative alkalimetric methods by the Fisher criterion (Fexp<Ftabl) was found to be the same. The proposed sensors can be used in analytical laboratories for quality control of foodstuffs and pharmaceuticals. 

Author Biographies

Kateryna Matorina, Oles Honchar Dnipropetrovsk National University Gagarina 72, Dnipropetrovsk, Ukraine, 49010

Associated Professor, Candidate of Chemical Sciences

The department of Analytical Chemistry

Olena Podpletnia, State establishment «Dnipropetrovsk Medical Academy» Dzerzhinsky str., 9, Dnipropetrovsk, Ukraine, 49044

Professor, Doctor of Pharmacy

The department of General and Сinical pharmacy

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Published

2016-08-30

How to Cite

Matorina, K., & Podpletnia, O. (2016). Development of potentiometric sensors for determining the concentration of ethan-1,2-dicarboxylic and 2-hydroxybenzoic acids. Eastern-European Journal of Enterprise Technologies, 4(10(82), 16–23. https://doi.org/10.15587/1729-4061.2016.75385

Issue

Vol. 4 No. 10(82) (2016): Ecology

Section

Ecology

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Copyright (c) 2016 Kateryna Matorina, Olena Podpletnia

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