Розкриття досліджень рідкого диму з рисового лушпиння як інгібітора зеленої корозії м'якої сталі під 1 М HCl

Автор(и)

DOI:

https://doi.org/10.15587/1729-4061.2022.265086

Ключові слова:

рідкий дим, інгібітор зеленої корозії, зола лушпиння рису, хемосорбція

Анотація

Робота забезпечує більш всебічну розробку рідкого диму із золи рисового лушпиння (ЗРЛ). Примітно, що дослідження зосереджено на взаємодії між первинними молекулами інгібітору та м'якої сталі, включаючи термодинамічний розрахунок та обробку поверхні при додаванні інгібітору. Електрохімічна спектроскопія імпедансу та потенціодинамічна поляризація були використані для оцінки антикорозійного захисту ЗРЛ. Раман-спектроскопію до та після додавання інгібітору ЗРЛ використовували для порівняння адсорбованої функціональної групи інгібіторів. При цьому термодинамічний розрахунок адсорбції інгібітору визначає види адсорбції інгібітора. В результаті процесу адсорбції був застосований скануючий електронний мікроскоп з енергодисперсійним рентгенівським випромінюванням (СЕМ-ЕРВ) у поєднанні з атомно-силовою мікроскопією (АСМ) та тестом контактного кута, щоб виявити обробку поверхні та зміну елементного складу після додавання 80 частин на мільйон інгібітора. Результати ФП та ЕІС показують значне зниження щільності струму при –2,75 мкА·см2 у розчині з концентрацією 80 частин на мільйон за максимальної ефективності інгібування 99,82 %. Краще інгібування корелює з адсорбцією Si-OH, C-C, C-O-C, C=O, складною структурою і -OH при хвильових числах 458, 662, 1095, 1780 та 3530 см-1. Рідкий дим показує значну площу захисної поверхні 0,9982 та високу константу адсорбції (Kадс) 11,648. Розрахункове значення ΔGадс, що дорівнює –6,59 кДж/моль, свідчить про хемосорбцію в природі. У той же час прогнозується, що комбінація розчину з концентрацією 20 та 80 частин на мільйон адсорбується горизонтально, щоб зменшити контакт між розчином та субстратом, як показано в результатах СЕМ та АСМ. Це також збільшує контактний кут та відповідну гідрофобність

Спонсор дослідження

  • The author gratefully thanks the Ministry of Research and Technology/National Research and Innovation Agency for the financial support of contract number NKB-1008/UN2.RST/HKP.05.00/2022.

Біографії авторів

Agus Kaban, Universitas Indonesia

Master of Engineering, Graduate Student

Prof Johny Wahyuadi Laboratory

Department of Metallurgical and Materials Engineering

Wahyu Mayangsari, Research Center for Metallurgy-National Research and Innovation Agency

Master of Engineering, Researcher

Mochammad Anwar, Research Center for Metallurgy-National Research and Innovation Agency

Master of Science, Senior Researcher

Ahmad Maksum, Politeknik Negeri Jakarta

Doctor of Engineering, Lecturer

Research Center for Eco-Friendly Technology

Department of Mechanical Engineering

Taufik Aditiyawarman, Universitas Indonesia

Master of Science, Graduate Student

Prof Johny Wahyuadi Laboratory

Department of Metallurgical and Materials Engineering

Johny Soedarsono, Universitas Indonesia

Doctor of Engineering, Professor

Prof Johny Wahyuadi Laboratory

Department of Metallurgical and Materials Engineering

Aga Ridhova, Research Center for Metallurgy-National Research and Innovation Agency

Master of Engineering, Researcher

Rini Riastuti, Universitas Indonesia

Doctor of Engineering, Senior Lecturer

Prof Johny Wahyuadi Laboratory

Department of Metallurgical and Materials Engineering

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Розкриття досліджень рідкого диму з рисового лушпиння як інгібітора зеленої корозії м'якої сталі під 1 М HCl

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2022-10-30

Як цитувати

Kaban, A., Mayangsari, W., Anwar, M., Maksum, A., Aditiyawarman, T., Soedarsono, J., Ridhova, A., & Riastuti, R. (2022). Розкриття досліджень рідкого диму з рисового лушпиння як інгібітора зеленої корозії м’якої сталі під 1 М HCl. Eastern-European Journal of Enterprise Technologies, 5(6 (119), 41–53. https://doi.org/10.15587/1729-4061.2022.265086

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Технології органічних та неорганічних речовин